63 Robinson Road,# 04-18 Afro Asia Building Singapore 068894, Republic of Singapore : +65 - 6227 6365 : +65 - 6225 6286 : tradeasiaservices@gmail.com MATERIAL SAFETY DATA SHEET OF SODA ASH DENSE Section 1 : Product Identification Synonyms
: Carbonic acid, Sodium carbonate; disodium carbonate; soda ash
Molecular Weight : 105.99 Chemical Formula : Na2CO3
Section 2 : Composition/Information on Ingredients Ingredient Hazardous
Section 3 : Hazards Identification Emergency Overview -------------------------- DANGER! MAY CAUSE EYE BURNS. HARMFUL IF SWALLOWED OR INHALED. CAUSES IRRITATION TO SKIN AND RESPIRATORY TRACT. SAF-T-DATA(tm) Ratings (Provided here for your convenience) ----------------------------------------------------------------------------------------------------------- Health Rating : 1 - Slight Flammability Rating : 1 - Slight Reactivity Rating : 2 - Moderate Contact Rating : 3 - Severe (Life) Lab Protective Equip : GOGGLES & SHIELD; LAB COAT & APRON; VENT HOOD Storage Color Code : Green (General Storage) ----------------------------------------------------------------------------------------------------------- Potential Health Effects ---------------------------------- Inhalation: Inhalation of dust may cause irritation to the respiratory tract. Symptoms from excessive inhalation of dust may include coughing and difficult breathing. Excessive contact is known to cause damage to the nasal septum. Ingestion: Sodium carbonate is only slightly toxic, but large doses may be corrosive to the gastro-intestinal tract where symptoms may include severe abdominal pain, vomiting, diarrhea, collapse and death. Skin Contact: Excessive contact may cause irritation with blistering and redness. Solutions may cause severe irritation or burns.
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63 Robinson Road,# 04-18 Afro Asia Building S ingapore 068894, Republic of Singapore Phone : +65 - 6227 6365 : +65 - 6225 6286 : tradeasiaservices@gmail.com
Eye Contact: Contact may be corrosive to eyes and cause conjuctival edema and corneal destruction. Risk of serious injury increases if eyes are kept tightly closed. Other symptoms may appear from absorption of sodium carbonate into the bloodstream via the eyes. Chronic Exposure: Prolonged or repeated skin exposure may cause sensitization. Aggravation of Pre-existing Conditions: No information found. Section 4 : First Aid Measures Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Ingestion: If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. Get medical attention immediately. Skin Contact: Immediately flush skin with plenty of soap and water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse. Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately. Note to Physician: Consider endoscopy in al suspected cases of sodium carbonate poisoning. Perform blood analysis to determine if dehydration, acidosis, or other electrolyte imbalances occurred. Section 5: Fire Fighting Measures Fire: Not considered to be a fire hazard. Explosion: Not considered an explosion hazard, but sodium carbonate may explode when applied to redhot aluminum. Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire. Special Information: Use protective clothing and breathing equipment appropriate for the surrounding fire.
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63 Robinson Road,# 04-18 Afro Asia Building S ingapore 068894, Republic of Singapore Phone : +65 - 6227 6365 : +65 - 6225 6286 : tradeasiaservices@gmail.com Section 6 : Accidental Release Measures Ventilate area of leak or spil . Wear appropriate personal protective equipment as specified in Section 8. Spills: Sweep up and containerize for reclamation or disposal. Vacuuming or wet sweeping may be used to avoid dust dispersal.
Section 7 : Handling and Storage Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Isolate from incompatible substances. Containers of this material may be hazardouswhen empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product. Section 8 : Exposure Controls/Personal Protection Airborne Exposure Limits: None established. Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details. Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn. If oil particles (e.g. lubricants, cutting fluids, glycerine, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face positivepressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres. Skin Protection: Wear protective gloves and clean body-covering clothing. Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
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63 Robinson Road,# 04-18 Afro Asia Building S ingapore 068894, Republic of Singapore Phone : +65 - 6227 6365 : +65 - 6225 6286 : tradeasiaservices@gmail.com Section 9 : Physical and Chemical Properties Appearance : White powder or granules. : Odorless. Solubility : 45.5 g/100 ml water @ 100C (212F) Specific Gravity : 2.53 pH : 11.6 Aqueous solution % Volatiles by volume @ 21C (70F) : 0 Boiling Point : Decomposes. Melting Point : 851C (1564F) Vapor Density (Air=1) : No information found. Vapor Pressure (mm Hg) : No information found. Evaporation Rate (BuAc=1) : No information found. Section 10 : Stability and Reactivity Stability: Stable under ordinary conditions of use and storage. Hygroscopic. Readily absorbs moisture from the air. Solutions are strong bases. Hazardous Decomposition Products: Oxides of carbon and sodium oxide. Hazardous Polymerization: Will not occur. Incompatibilities: Fluorine, aluminum, phosphorous pentoxide, sulfuric acid, zinc, lithium, moisture, calcium hydroxide and 2,4,6-trinitrotoluene. Reacts violently with acids to form carbon dioxide. Conditions to Avoid: Moisture, heat, dusting and incompatibles. Section 11 : Toxicological Information Oral rat LD50: 4090 mg/kg; inhalation rat LC50: 2300 mg/m3/2H; irritation eye rabbit: 50 mg severe; investigated as a mutagen, reproductive effector. --------\Cancer Lists\------------------------------------------------------ ---NTP Carcinogen--- Ingredient Known Anticipated IARC Category ------------------------------------ ----- ----------- ------------- Sodium Carbonate (497-19-8) No No None Section 12 : Ecological Information Environmental Fate: No information found. Environmental Toxicity: 96 Hr LC50 Lepomis macrochirus: 300 mg/L [static]; 48 Hr EC50 Daphnia magna: 265 mg/L
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63 Robinson Road,# 04-18 Afro Asia Building S ingapore 068894, Republic of Singapore Phone : +65 - 6227 6365 : +65 - 6225 6286 : tradeasiaservices@gmail.com Section 13 : Disposal Considerations Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements. Section 14 : Transport Information DOT Proper Shipping Name : Packing Group(s) Hazard Class Description Section 15: Regulatory Information --------\Chemical Inventory Status - Part 1\--------------------------------- Ingredient TSCA EC Japan Australia ----------------------------------------------- ---- --- ----- --------- Sodium Carbonate (497-19-8) Yes Yes Yes Yes--------\Chemical Inventory Status - Part 2\-------------- ------------------- --Canada-- Ingredient Korea DSL NDSL Phil. ----------------------------------------------- ----- --- ---- ----- Sodium Carbonate (497-19-8) Yes Yes No Yes --------\Federal, State & International Regulations - Part 1\---------------- -SARA 302- ------SARA 313------ Ingredient RQ TPQ List Chemical Catg. ----------------------------------------- --- ----- ---- -------------- Sodium Carbonate (497-19-8) No No No No --------\Federal, State & International Regulations - Part 2\---------------- -RCRA- -TSCAIngredient CERCLA 261.33 8(d) ----------------------------------------- ------ ------ ------ Sodium Carbonate (497-19-8) No No No Chemical Weapons Convention: No TSCA 12(b): No CDTA: No SARA 311/312: Acute: Yes Chronic: No Fire: No Pressure: No Reactivity: No (Pure / Solid)
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63 Robinson Road,# 04-18 Afro Asia Building S ingapore 068894, Republic of Singapore Phone : +65 - 6227 6365 : +65 - 6225 6286 : tradeasiaservices@gmail.com
Section 16: Other Information Notice
: We belive the statements, technical information and recommendations
contained herein are reliable, but they are given without warranty or gurantee of any kind, express or implied, and we assume no responbility for any loss, damage, or expense, direct or consequential, arising out of their use.
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Cuyahoga County S M O K I N G C E S S A T I O N Insurance Carrier Cessation Program The County will cover the following items to assist you in quitting Lunch-n-Learn Schedule smoking: • Nicotrol Spray/Inhaler @ 100% - max 2 Rxs • August 10 – Administration Building Room, noon – 1:00 p.m. Other resources to assist you in • August 24 – Virg
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