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SAFETY DATA SHEET Date of issue: 26.11.2009 Updating date: 26.11.2009 1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING 1.1 Identification of the product: METAL BOX – REPAIR BOX WITH ALUMINUM NET 1.2. Use of the substance/mixture: 2-component putty based on unsaturated polyester resin with aluminium net. Used for filling up the holes in a car body. 1.3. Manufacturer/supplier identification: Harmful product. Harmful by inhalation. Irritating to eyes and skin. Flammable liquid. Avoid contact with strong oxidants. 3. COMPOSITION/INFORMATION ON INGREDIENTS Administer Dexamethasone aerosol (Auxiloson, Pulmicort) for inhalation. Ensure calm, quiet surroundings, fresh air, and seek medical advice. Take off soiled clothes. Wash off with plenty of lukewarm water (at least 15 minutes). Consult a doctor in the event of skin reaction. Hold the eyes open and rinse immediately with plenty of lukewarm water (at least 15 minutes). Contact with ophthalmologist. Do not provoke vomiting (risk of choking). Rinse mouth with lukewarm water. Give 1-2 glasses of lukewarm water. Medical help is required. Powder, foam resistant to alcohols, carbon dioxide, watermist. Fire may cause the generation of carbon monoxide. Fireman has to wear self-contained breathing apparatus and protective clothing. Cool adjacent tanks by spraying water from a safe distance. PERSONAL PROTECTION: Eliminate sources of ignitron. Ensure sufficient ventilation in his room. Avoid direct contact with the released substance. Avoid contact with skin and eyes. Put on protective equipment see chapter 8. PROTECTION OF THE ENVIRONMENT: Prevent to get through to the sewage system, to the surface water, underground water, to the soil. In case of a major spillage the affected area should be separate with bounds. ACTION IN CASE OF SPILLAGE: Seal the container, damaged containers should be placed in emergency containers. Besprinkle spillage, use e.g. mica, wood flour, sand. Remove the substance mechanically and put to emergency containers. For further disposal measures: see charter 13. SAFETY DATA SHEET METAL BOX Date of issue: 26.11.2009 Updating date: 26.11.2009 Keep away from heat and sources of fire. Do not smoke. Do not inhale vapours. Avoid contact with skin and eyes. Take precautionary measures against electrostatic loading. Use only in well ventilated place. Keep in sealed containers in cool, well-ventilated place. Storage in the vicinity of a large quantity of organic peroxides or strong oxidants is prohibited. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Personal protective measures should respond to the requirements of the Regulation of Minister of Economy of 21st December 2005 regarding principal requirements for personal protective measures. (Law Gazette 2005 No 259, item 2173) Gas mask with „A” type-absorbing canister (according to EN 141). Protective gloves suitable for handling solvents (nitrile, rubber, niton), according to PN-EN 374-3:1999 Suitable protective clothing (antistatic, impregnated clothing) Topical stays and exhausting ventilation. People suffering from oversensitivity of respiratory system (ex. asthma, chronic inflammatory disorder of the respiratory system) should not enter in contact with the product. Regulation of Minister of Labour and Social Policy, dated 26 September 1997, on behalf of general regulations of health and safety at work (Law Gazette No 129, item 844 with later amendment; Law Gazette 2022 No 91, item 811; uniform text Law Gazette 2003 No 169, item 1650 with later amendment; Law Gazette 2007 No 49, item 330. Regulation of Minister of Health, dated 3 November 2008, changing the regulation of health and safety at work related to chemical factors present at a workplace (Law Gazette 2008 No 203, item 1275). Medical examinations of workers in accordance with Health Code and according to Regulation of Minister of Health, dated 30 May 1996, on behalf of perform medical examinations of workers, the range of preventive health care for workers and medical opinions released for purposes stated in the Labour Code (Law Gazette 1996 No 69, item 332 with later amendment, Law Gazette 1998 No 159, item 1057 and Law Gazette 2001 No 37, item 451. Values of the highest acceptable concentrations according to Regulation of Minister of Labour and Social Policy, dated November 29th, 2002, on behalf of maximum acceptable concentration and intensity of harmful factors in a workplace (Law Gazette No 217, item 1833 with later amendment Law Gazette 2005 No 212, item 1769; Law Gazette 2007 No 161, item 1142 and Law Gazette 2009 No 105, item 873: Monitoring according to Regulation of Minister of Health, dated 20 April 2005 on behalf of research and measurements of harmful factors in a workplace for health in work environment (Law Gazette No 73, item 645 with later amendment; Law Gazette 2007 No 241, item 1772) PN-EN 488:2009 Air in work environments -- General requirements regarding the measurement procedures. PN-EN-689: 2002. Air in work places – guidelines for estimating the risk of chemical inhalation con the basis comparison with acceptable values and measurement strategy. PN-Z-04008-7:2002 Air clarity protection. Taking samples. The rules of taking air samples in work environment and interpretation of results. PN-86/Z-04152.02 Air clarity protection – Research on the content of styrene – Marking styrene in a workplace using the method of as chromatography with enriching the sample. SAFETY DATA SHEET METAL BOX Date of issue: 26.11.2009 Updating date: 26.11.2009 The product remains stable under normal conditions. Carbon monoxide and other toxic gasses are generated as aa result of DECOMPOSITION PRODUCTS: thermal decomposition. 11. TOXICOLOGICAL INFORMATION (literature data) TOXICITY: Toxicological studies at the preparation are not available. Estimation on the basis of the data regarding LCL0 (human, inhalation) 10000 ppm/0.5 hour. Skin: irritating to skin and mucous membranes. Headache and vertigo, fatigue, decreased muscle power, sleepiness and, in exceptional instances, loss of consciousness. If swallowed, the substance may cause irritation of the alimentary tract, nausea, vomiting, and diarrhoea. 12. ECOLOGICAL INFORMATION (literature data) Ecological studies at the preparation are not available. Estimation on the basis of the data regarding dangerous components of the product. The product is very poorly soluble in water. Keep away from the sewage system, surface water, underground water, and soil. Number in catalogue includes substance danger to water: Product must be disposed of by special means in accordance with local regulations. Remains of product in the tin should be carefully remove and harden using suitable hardener. ATTENTION: remains should be hardened in small portions far from flammable substances. Much amount of heat is emitting in the time of reaction! Harden product is not harmfully substance. Tin carefully clean is not harmful waste. SAFETY DATA SHEET METAL BOX Date of issue: 26.11.2009 Updating date: 26.11.2009 GENERAL INFORMATION: Do not transport with materials class 1 (with the exception of materials class 1.4S) and with some of materials class 4.1 and 5.2. Avoid direct contact with materials class 5.1 and 5.2 in the time of transport. Do not use naked flame and do not smoke. Putty together with hardener in collective packaging: RESIN SOLUTIONS, class 3, UN 3269, packaging group III, Ems: F-E, S-D Safety data sheet in accordance with: Act on behalf of substances and chemical preparations, dated 11 January 2001 (Law Gazette No. 11, item 84 with later amendment Law Gazette 2006 No 120, item 826; Law Gazette 2009 No. 20, item 106 – uniform text, No. 152, item 1222 – uniform text. Regulation of Minister of Health, dated 28 September 2005 on behalf of list of dangerous substances with their classification and marking (Law Gazette No. 201, item 1674, article 2). Regulation of Minister of Health, dated 2 September 2003 on behalf of criteria and methods of classification of substances and chemical preparations (Law Gazette No. 171, item 1666 (article 2) with later amendments; Law Gazette 2004 No 243 item 2440; Law Gazette 2007 No 174, item 1222; Law Gazette 2009 No 43, item 353). Order of Minister of Health, dated November 13th, 2007 on behalf of Safety Data Sheet (Law Gazette 2007 No 215, item 1588). Regulation of Minister of Labour and Social Policy, dated 5 July 2004 on behalf of restrictions, prohibitions or conditions of production or use of dangerous substances and harmful components and products that contain them (Law Gazette No 168, item 1762 with later amendment Law Gazette 2006 No 239, item 1731, Law Gazette 2007 No 1, item 1, Law Gazette 2007 No 116, item 806, Law Gazette 2008 No 190, item 1163). Regulation of Minister of Labour and Social Policy, dated 1 December 2004 on behalf of substances, components, factors or technological processes of carcinogenic or mutagenic action in work environment (Law Gazette 2004 No 280, item 2771 with later amendment; Law Gazette 2005 No 160, item 1356). Regulation of Minister of Health, dated 5 March 2009 on behalf of markings on packing of dangerous substances and chemical preparations and some chemical substances (Law Gazette 2009 No 53, item 439). Regulation of Minister of Environment, dated 27 September 2001, on behalf of catalogue of waste material (Law Gazette No 112, item 1206 (art. 13). Regulation of Minister of Labour and Social Policy, dated 29 November 2002 on behalf of maximum permissible concentrations and intensity of harmful factors in work environment (Law Gazette No 217, item 1833, 2002 with later amendments; Law Gazette 2005 No 212, item 1769; Law Gazette 2007 No 161, item 1142 and Law Gazette 2009 No 105, item 873). Regulation of Minister of Health, dated 20 April 2005, in the Matter of Admissible Concentrations and Intensity of Factors Harmful for Health in Workplace Environment (Law Gazette No 73, item 645 with later amendment Law Gazette 2007 No 241, item 1772 (article 8). Regulation of Minister of Health, dated 3 November 2008, amending the regulation on behalf of health and safety in work related to the presence of chemical factors in a workplace (Law Gazette 2008 No 203, item 1275 (article 8). Government Statement of 23rd March 2007 on behalf of coming into effect of amendments regarding Appendices A and B of the European Contract for international road transport of dangerous products, constructed in Geneva on 30th September 1957. (Law Gazette 2007 No 99, item 667 appendix: European contract regarding international road transport of dangerous products. ADR 2009-2011 (article 14), IMDG Code 2008 Edition (article 14) Regulation (UE) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC. Official Journal of the European Union L 136, dated May 29th, 2007, with later amendment OJ EU L 304 dated November 22nd, 2007, OJ EU L268 dated October 9th, 2008, OJ EU No 46 dated February 17th, 2009, OJ EU L164 dated June 26th, 2009. Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006 (OJ L 353, 31.12.2008) SAFETY DATA SHEET METAL BOX Date of issue: 26.11.2009 Updating date: 26.11.2009 Commission Regulation (EC) No 790/2009 of 10 August 2009 amending, for the purposes of its adaptation to technical and scientific progress, Regulation (EC) No 1272/2008 of the European Parliament and of the Council on classification, labelling and packaging of substances and mixtures. (OJ L 235, 05.09.2009) CONTAINS: If swallowed, seek medical advice immediately and show this container or label. Packaging has a touchable sign: Regulation of Minister of Health of 30th April 2004 on behalf of dangerous substances and products which have packaging difficult to open by kids and a touchable warning of danger (Law Gazette No 128, item 1348). Full text of the R-Phrases from section 2 and 3: R10 Flammable; R20 Harmful by inhalation; R36/38 Irritating to eyes and skin. Information contained herein is based on our current knowledge. This document does not constitute a warranty for product characteristics. Issued by: RANAL Sp. z o.o.

Source: http://www.ranal.pl/upload/articles/20/METAL-BOX_ENG.pdf

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