PRODUCT NAME GARDEN PRO ANT KILLER 1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER Supplier Name PASCOE'S PTY LTD
14 Casino Street, Welshpool, WA, AUSTRALIA, 6106
Telephone Emergency
info@pascoes.com.au, pascoes@pascoes.com.au
Synonym(s) MSDS Date 2. HAZARDS IDENTIFICATION NOT CLASSIFIED AS HAZARDOUS ACCORDING TO NOHSC CRITERIA NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE Subsidiary Risk(s) None Allocated Pkg Group Hazchem Code 3. COMPOSITION / INFORMATION ON INGREDIENTS Ingredient 4. FIRST AID MEASURES
If in eyes, hold eyelids apart and flush the eye continuously with running water. Continue flushing until advised tostop by the PIC or a doctor, or for at least 15 minutes. Inhalation
If over exposure occurs leave exposure area immediately. If irritation persists, seek medical attention.
Gently flush affected areas with water. Seek medical attention if irritation develops. Ingestion
For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor. Advice to Doctor PRODUCT NAME GARDEN PRO ANT KILLER 5. FIRE FIGHTING MEASURES Flammability
Non flammable. No fire or explosion hazard exists.
Non flammable. Evacuate area and contact emergency services. Remain upwind and notify those downwind of
Explosion
hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combatingfire. Use waterfog to cool intact containers and nearby storage areas. Extinguishing
Non flammable. Prevent contamination of drains or waterways, absorb runoff with sand or similar. Hazchem Code 6. ACCIDENTAL RELEASE MEASURES Spillage
If spilt (bulk), wear dust-proof goggles, PVC/rubber gloves, a Class P1 (Particulate) respirator (where an inhalationrisk exists) and coveralls or protective clothing. Moisten with water to prevent a dust hazard. 7. STORAGE AND HANDLING
Store in cool, dry, well ventilated area, out of direct sunlight and out of the reach of children, removed fromoxidising agents, alkalis and foodstuffs. Ensure containers are adequately labelled, protected from physicaldamage and sealed when not in use. Handling
Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skincontact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating,drinking and smoking in contaminated areas. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Stds Biological Limits Engineering
Ensure adequate natural ventilation. Maintain dust levels below the recommended exposure standard. Controls
Personal Protective Equipment is not required under normal conditions of use. When using large quantities orwhere heavy contamination is likely, wear dust-proof goggles and rubber or PVC gloves. Where an inhalation riskexists, wear a Class P1 (Particulate) Respirator. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Solubility (water) Specific Gravity % Volatiles Vapour Pressure Flammability Vapour Density Flash Point Boiling Point Upper Explosion Limit Melting Point Lower Explosion Limit Evaporation Rate Autoignition Temperature 10. STABILITY AND REACTIVITY Material to Avoid
Incompatible with oxidising agents (eg. hypochlorites, peroxides) and alkalis (eg. hydroxides). Decomposition
May evolve toxic gases if heated to decomposition. PRODUCT NAME GARDEN PRO ANT KILLER 11. TOXICOLOGICAL INFORMATION Health Hazard
Low toxicity. Restrict application to target areas only and avoid eye-skin contact and dust inhalation. Due to the
low levels of active ingredients in this product, adverse health effects are not anticipated with normal use. Nocumulative or chronic effects have been reported. Pyrethrins have consistently demonstrated low toxicity tohumans.
Low to moderate irritant. Exposure may result in irritation, pain and redness. Inhalation
Low to moderate irritant - low toxicity. Over exposure may result in mucous membrane irritation of the respiratorytract and sneezing. At high levels, pyrethrins may cause breathing difficulties (wheezing) and sensitisation withasthma like symptoms.
Low irritant. Prolonged and repeated contact may result in irritation, skin rash and dermatitis. Ingestion
Low toxicity. Ingestion may result in headache, nausea, vomiting, gastrointestinal irritation and diarrhoea. Toxicity Data
PERMETHRIN (52645-53-1) LC50 (Inhalation): 485 mg/m3 (rat) LD50 (Ingestion): 383 mg/kg (rat) LD50 (Skin): 1750 mg/kg (rat)
12. ECOLOGICAL INFORMATION Environment
Limited ecotoxicity data was available for this product at the time this report was prepared. Ensure appropriatemeasures are taken to prevent this product from entering the environment. 13. DISPOSAL CONSIDERATIONS Waste Disposal
For small amounts, cover with moist sand or similar, collect and dispose of to an approved landfill site. Avoidgenerating dust. Contact the manufacturer for additional information. Legislation
Dispose of in accordance with relevant local legislation. 14. TRANSPORT INFORMATION NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE Shipping Name Subsidiary Risk(s) Pkg Group Hazchem Code 15. REGULATORY INFORMATION Poison Schedule
A poison schedule number has not been allocated to this product using the criteria in the Standard for the UniformScheduling of Drugs and Poisons (SUSDP).
All chemicals listed on the Australian Inventory of Chemical Substances (AICS). 16. OTHER INFORMATION Additional
RESPIRATORS: In general the use of respirators should be limited and engineering controls employed to avoid
Information
exposure. If respiratory equipment must be worn ensure correct respirator selection and training is undertaken. Remember that some respirators may be extremely uncomfortable when used for long periods. The use of airpowered or air supplied respirators should be considered where prolonged or repeated use is necessary.
SYNERGISM - ANTAGONISM: Ingredients in this product may act together to aggravate or reduce adverseeffects. Accordingly the time weighted average concentration (TWA) provided for single ingredients should beconsidered as a guide only and all due care exercised when handling.
ABBREVIATIONS:ADB - Air-Dry Basis. BEI - Biological Exposure Indice(s)CAS# - Chemical Abstract Service number - used to uniquely identify chemical compounds. CNS - Central Nervous System. IARC - International Agency for Research on Cancer. M - moles per litre, a unit of concentration. mg/m3 - Milligrams per cubic metre. PRODUCT NAME GARDEN PRO ANT KILLER
NOS - Not Otherwise Specified. pH - relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline). ppm - Parts Per Million. TWA/ES - Time Weighted Average or Exposure Standard.
HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factors including: frequencyand duration of use; quantity used; effectiveness of control measures; protective equipment used and method ofapplication. Given that it is impractical to prepare a Chem Alert report which would encompass all possiblescenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.
PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this Chem Alert report is provided as a guide only. Factors such as method of application, working environment, quantity used, product concentration and theavailability of engineering controls should be considered before final selection of personal protective equipment ismade.
COLOUR RATING SYSTEM: RMT has assigned all Chem Alert reports a colour rating of Green, Amber or Red forthe sole purpose of providing users with a quick and easy means of determining the hazardous nature of aproduct. Safe handling recommendations are provided in all Chem Alert reports so as to clearly identify how userscan control the hazards and thereby reduce the risk (or likelihood) of adverse effects. As a general guideline, aGreen colour rating indicates a low hazard, an Amber colour rating indicates a moderate hazard and a Red colourrating indicates a high hazard.
While all due care has been taken by RMT in the preparation of the Colour Rating System, it is intended as aguide only and RMT does not provide any warranty in relation to the accuracy of the Colour Rating System. As faras is lawfully possible, RMT accepts no liability or responsibility whatsoever for the actions or omissions of anyperson in reliance on the Colour Rating System. Report Status
This document has been compiled by RMT on behalf of the manufacturer of the product and serves as themanufacturer's Material Safety Data Sheet ('MSDS').
It is based on information concerning the product which has been provided to RMT by the manufacturer orobtained from third party sources and is believed to represent the current state of knowledge as to the appropriatesafety and handling precautions for the product at the time of issue. Further clarification regarding any aspect ofthe product should be obtained directly from the manufacturer.
While RMT has taken all due care to include accurate and up-to-date information in this MSDS, it does not provideany warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss,injury or damage (including consequential loss) which may be suffered or incurred by any person as aconsequence of their reliance on the information contained in this MSDS. Prepared By
Risk Management Technologies5 Ventnor Ave, West PerthWestern Australia 6005Phone: +61 8 9322 1711Fax: +61 8 9322 1794Email: info@rmt.com.auWeb: www.rmt.com.au
MSDS Date: 17 September 2007 End of Report
World Health Organisation. Prevention of Deafness and Hearing Impairment. Factsheet:Deafness and Hearing Impairment. http://www.who.int/mediacentre/factsheets/fs300/en/index.html. Last accessed 4/11/2009. Page 24 of 24 6 References CIA World Factbook. Kenya. https://www.cia.gov/library/publications/the-world- factbook/geos/ke.html. Last accessed 5/11/2009. Gaskins, Susan. 1999. Special
The Open Women’ Health Journal, 2007, 1, 1-3 1 Prolonged Post-Treatment Genital Anesthesia and Sexual Dysfunction Following Discontinuation of Citalopram and the Atypical Antidepressant Nefazodone Department of Obstetrics and Gynecology, Texas Tech University Health Sciences Center, School of Medicine, 1400 Coulter Drive, Amarillo, Texas 79106 USA Abstract: SSRI therapy is