SECTION 1 - IDENTIFICATION OF CHEMICAL PRODUCT AND COMPANY Substance: Trade Name: Wash-Out Product Use:
Commercial hand dishwashing liquid. Considered safe to use in food areas, meet the standards set by AQIS when used as directed on the label.
Creation Date: February, 2006 Revision Date: January, 2012 and is valid for 5 years from this date SECTION 2 - HAZARDS IDENTIFICATION Statement of Hazardous Nature This product is classified as: Not classified as hazardous according to the criteria of NOHSC Australia.
Not a Dangerous Good according to the Australian Dangerous Goods (ADG) Code.
Risk Phrases: Not Hazardous - No criteria found. Safety Phrases: S25, S37. Avoid contact with eyes. Wear suitable gloves. SUSDP Classification: None allocated. ADG Classification: None allocated. Not a Dangerous Good under the ADG Code. UN Number: None allocated Emergency Overview Physical Description & colour: Viscous green liquid. Odour: Mint fragrance. Major Health Hazards: no significant risk factors have been found for this product. Potential Health Effects Inhalation Short term exposure: Available data indicates that this product is not harmful. However product may be mildly irritating, although unlikely to cause anything more than mild transient discomfort. Long Term exposure: No data for health effects associated with long term inhalation. Skin Contact: Short term exposure: Available data indicates that this product is not harmful. It should present no hazards in normal use. However product may be mildly irritating, but is unlikely to cause anything more than mild discomfort which should disappear once contact ceases. Long Term exposure: No data for health effects associated with long term skin exposure. Eye Contact: Short term exposure: This product is believed to be mildly irritating, to eyes, but is unlikely to cause anything more than mild transient discomfort. Long Term exposure: No data for health effects associated with long term eye exposure. Ingestion: Short term exposure: Significant oral exposure is considered to be unlikely. However, this product is believed to be mildly irritating to mucous membranes but is unlikely to cause anything more than mild transient discomfort. Long Term exposure: No data for health effects associated with long term ingestion. Carcinogen Status: NOHSC: No significant ingredient is classified as carcinogenic by NOHSC. NTP: No significant ingredient is classified as carcinogenic by NTP. IARC: No significant ingredient is classified as carcinogenic by IARC. SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS Ingredients TWA (mg/m3) STEL (mg/m3) Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand) Product Name: Wash-Out Page: 2 of 4 This revision issued: January, 2012
This is a commercial product whose exact ratio of components may vary slightly. Minor quantities of other non hazardous ingredients are also possible. The TWA exposure value is the average airborne concentration of a particular substance when calculated over a normal 8 hour working day for a 5 day working week. The STEL (Short Term Exposure Limit) is an exposure value that may be equalled (but should not be exceeded) for no longer than 15 minutes and should not be repeated more than 4 times per day. There should be at least 60 minutes between successive exposures at the STEL. The term "peak "is used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly.
SECTION 4 - FIRST AID MEASURES General Information:
You should call The Poisons Information Centre if you feel that you may have been poisoned, burned or irritated by this product. The number is 13 1126 from anywhere in Australia (0800 764 766 in New Zealand) and is available at all times. Have this MSDS with you when you call.
Inhalation: First aid is not generally required. If in doubt, contact a Poisons Information Centre or a doctor. Skin Contact: Irritation is unlikely. However, if irritation does occur, flush with lukewarm, gently flowing water for 5 minutes or until chemical is removed. Eye Contact: Immediately flush the contaminated eye(s) with lukewarm, gently flowing water for 5 minutes or until the product is removed, while holding the eyelid(s) open. Obtain medical advice immediately if irritation occurs. Take special care if exposed person is wearing contact lenses. Ingestion: If product is swallowed or gets in mouth, do NOT induce vomiting; wash mouth with water and give some water to drink. If symptoms develop, or if in doubt contact a Poisons Information Centre or a doctor. SECTION 5 - FIRE FIGHTING MEASURES Fire and Explosion Hazards: There is no risk of an explosion from this product under normal circumstances if it is involved in a fire. Only small quantities of decomposition products are expected from this products at temperatures normally achieved in a fire. This will only occur after heating to dryness. Fire decomposition products from this product are likely to be irritating if inhaled. Extinguishing Media: Not Combustible. Use extinguishing media suited to burning materials. Fire Fighting: If a significant quantity of this product is involved in a fire, call the fire brigade. Flash point: Upper Flammability Limit: Lower Flammability Limit: Autoignition temperature: Flammability Class: SECTION 6 - ACCIDENTAL RELEASE MEASURES Accidental release: Minor spills do not normally need any special cleanup measures. In the event of a major spill, prevent spillage from entering drains or water courses. As a minimum, wear overalls, goggles and gloves. Suitable materials for protective clothing include rubber, PVC. Eye/face protective equipment should comprise as a minimum, protective glasses and, preferably, goggles. If there is a significant chance that vapours or mists are likely to build up in the cleanup area, we recommend that you use a respirator. Usually, no respirator is necessary when using this product. However, if you have any doubts consult the Australian Standard mentioned below (section 8). Stop leak if safe to do so, and contain spill. Absorb onto sand, vermiculite or other suitable absorbent material. If spill is too large or if absorbent material is not available, try to create a dike to stop material spreading or going into drains or waterways. Sweep up and shovel or collect recoverable product into labelled containers for recycling or salvage, and dispose of promptly. Recycle containers wherever possible after careful cleaning. After spills, wash area preventing runoff from entering drains. If a significant quantity of material enters drains, advise emergency services. This material may be suitable for approved landfill. Ensure legality of disposal by consulting regulations prior to disposal. Thoroughly launder protective clothing before storage or re-use. Advise laundry of nature of contamination when sending contaminated clothing to laundry. SECTION 7 - HANDLING AND STORAGE Handling: Keep exposure to this product to a minimum, and minimise the quantities kept in work areas. Check Section 8 of this MSDS for details of personal protective measures, and make sure that those measures are followed. The measures detailed below under "Storage" should be followed during handling in order to minimise risks to persons using the product in the workplace. Also, avoid contact or contamination of product with incompatible materials listed in Section 10. MATERIAL SAFETY DATA SHEET Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand) Product Name: Wash-Out Page: 3 of 4 This revision issued: January, 2012 Storage: Make sure that the product does not come into contact with substances listed under "Incompatibilities" in Section 10. Check packaging - there may be further storage instructions on the label. SECTION 8 - EXPOSURE CONTROLS AND PERSONAL PROTECTION
The following Australian Standards will provide general advice regarding safety clothing and equipment:
Respiratory equipment: AS/NZS 1715, Protective Gloves: AS 2161, Industrial Clothing: AS2919, Industrial Eye Protection: AS1336 and AS/NZS 1337, Occupational Protective Footwear: AS/NZS2210. Exposure Limits TWA (mg/m3) STEL (mg/m3)
Exposure limits have not been established by NOHSC for any of the significant ingredients in this product.
No special equipment is usually needed when occasionally handling small quantities. The following instructions are for bulk handling or where regular exposure in an occupational setting occurs without proper containment systems. Ventilation: No special ventilation requirements are normally necessary for this product. However make sure that the work environment remains clean and that vapours and mists are minimised. Eye Protection: Eye protection such as protective glasses or goggles is recommended when this product is being used. Skin Protection: The information at hand indicates that this product is not harmful and that normally no special skin protection is necessary. However, we suggest that you routinely avoid contact with all chemical products and that you wear suitable gloves (preferably elbow-length) when skin contact is likely. Protective Material Types: We suggest that protective clothing be made from the following materials: rubber, PVC. Respirator: Usually, no respirator is necessary when using this product. However, if you have any doubts consult the Australian Standard mentioned above. SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES: Physical Description & colour: Viscous green liquid. Odour: Boiling Point: Freezing/Melting Point: Volatiles: Vapour Pressure:
2.37 kPa at 20°C (water vapour pressure).
Vapour Density: Specific Gravity: Water Solubility: Volatility: Odour Threshold: Evaporation Rate: Coeff Oil/water distribution: Autoignition temp: SECTION 10 - STABILITY AND REACTIVITY Reactivity: This product is unlikely to react or decompose under normal storage conditions. However, if you have any doubts, contact the supplier for advice on shelf life properties. Conditions to Avoid: None known. Incompatibilities: No particular Incompatibilities. Fire Decomposition: Only small quantities of decomposition products are expected from this products at temperatures normally achieved in a fire. This will only occur after heating to dryness. Carbon dioxide, and if combustion is incomplete, carbon monoxide and smoke. Water. Carbon monoxide poisoning produces headache, weakness, nausea, dizziness, confusion, dimness of vision, disturbance of judgment, and unconsciousness followed by coma and death. Polymerisation: This product will not undergo polymerisation reactions. SECTION 11 - TOXICOLOGICAL INFORMATION Local Effects: Target Organs: MATERIAL SAFETY DATA SHEET Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand) Product Name: Wash-Out Page: 4 of 4 This revision issued: January, 2012 Classification of Hazardous Ingredients
No ingredient mentioned in the List of Designated Hazardous Substances is present in this product at hazardous concentrations.
SECTION 12 - ECOLOGICAL INFORMATION SECTION 13 - DISPOSAL CONSIDERATIONS Disposal: There are many pieces of legislation covering waste disposal and they differ in each state and territory, so each user must refer to laws operating in their area. In some areas, certain wastes must be tracked. The Hierarchy of Controls seems to be common - the user should investigate: Reduce, Reuse, and Recycle and only if all else fails should disposal be considered. Note that properties of a product may change in use, so that the following suggestions may not always be appropriate. The following may help you in properly addressing this matter for this product. This product may be recycled if unused, or if it has not been contaminated so as to make it unsuitable for its intended use. If it has been contaminated, it may be possible to separate the contamination in some way. Only if neither of these options is suitable, consider landfill. SECTION 14 - TRANSPORT INFORMATION ADG Code: This product is not classified as a Dangerous Good. No special transport conditions are necessary unless required by other regulations. SECTION 15 - REGULATORY INFORMATION AICS: All of the significant ingredients in this formulation are compliant with NICNAS regulations. SECTION 16 - OTHER INFORMATION This MSDS contains only safety-related information. For other data see product literature. Acronyms:
Australian Code for the Transport of Dangerous Goods by Road and Rail
Australian Inventory of Chemical Substances
Chemical Abstracts Service Registry Number
Emergency action code of numbers and letters that provide information to emergency services especially firefighters
International Agency for Research on Cancer
National Occupational Health and Safety Commission
Standard for the Uniform Scheduling of Drugs & Poisons
THIS MSDS SUMMARISES OUR BEST KNOWLEDGE OF THE HEALTH AND SAFETY HAZARD INFORMATION OF THE PRODUCT AND HOW TO SAFELY HANDLE AND USE THE PRODUCT IN THE WORKPLACE. EACH USER MUST REVIEW THIS MSDS IN THE CONTEXT OF HOW THE PRODUCT WILL BE HANDLED AND USED IN THE WORKPLACE.
IF CLARIFICATION OR FURTHER INFORMATION IS NEEDED TO ENSURE THAT AN APPROPRIATE RISK ASSESSMENT CAN BE MADE, THE USER SHOULD CONTACT THIS COMPANY SO WE CAN ATTEMPT TO OBTAIN ADDITIONAL INFORMATION FROM OUR SUPPLIERS
OUR RESPONSIBILITY FOR PRODUCTS SOLD IS SUBJECT TO OUR STANDARD TERMS AND CONDITIONS, A COPY OF WHICH IS SENT TO OUR CUSTOMERS AND IS ALSO AVAILABLE ON REQUEST.
Please read all labels carefully before using product.
This MSDS is prepared for Chemical Cleaning Solutions Pty Ltd in accord with the NOHSC document
“National Code of Practice for the Preparation of Material Safety Data Sheets” 2nd Edition
Copyright Kilford & Kilford Pty Ltd, September, 2012.
MATERIAL SAFETY DATA SHEET Poisons Information Centre: 13 1126 from anywhere in Australia, (0800 764 766 in New Zealand)
Insecticides for Protecting Pine Trees from Mountain Pine John Ball, Forest Health Specialist, South Dakota Department of Agriculture, Extension Forestry Specialist, South Dakota State University Cooperative Extension Service; Kurt Allen, Entomologist, USDA Forest Service, Rapid City Service Center and Brian Garbisch, Forest Health Forester, South Dakota Department of Agriculture. Pestici
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