Msds_aqua impregnator for wood_en.xps

Safety data sheet
According to Regulatin 1907/2006/EC, Article 31 and Regulation 1272/2008/EC
1 Identification of the substance / mixture and of the company / undertaking
· Product identifier
· Trade name: Impregnator for wood "AQUA"
· Relevant identified uses of the substance or mixture and uses advised against
· Application of the substance / the preparation:
For impregnating of woodwork, garden furniture, fences, decorative wood elements, etc. · Details of the supplier of the safety data sheet
· Manufacturer / Supplier:
· Further information obtainable from: Phone: +359 32 674781 During normal opening time
· Emergency telephone number
+359 2 9154 409 Bulgarian National Toxicological Information Centre 2 Hazards identification
· Classification of the substance or mixture
· Classification according to Regulation (EC) No 1272/2008:
Aquatic Chronic 1 H410 Very toxic to aquatic life with long lasting effects. · Classification according to Directive 67/548/EEC or Directive 1999/45/EC:
 N; Dangerous for the environment R50/53: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic · Information concerning particular hazards for human and environment:
The product has to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the EU" in the latest valid version. · Classification system:
The classification is according to the latest editions of the EU-lists, and extended by company and literature · Label elements
· Labelling according to EU guidelines:
The product has been classified and marked in accordance with EU Directives / Ordinance on Hazardous · Code letter and hazard designation of product:
 N Dangerous for the environment · Risk phrases:
50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Safety data sheet
According to Regulatin 1907/2006/EC, Article 31 and Regulation 1272/2008/EC
Trade name: Impregnator for wood "AQUA"
· Safety phrases:
29/56 Do not empty into drains, dispose of this material and its container at hazardous or special waste Use appropriate container to avoid environmental contamination. This material and its container must be disposed of as hazardous waste. · Special labelling of certain preparations:
Contains Permethrin. May produce an allergic reaction. · Other hazards
· Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
3 Composition / information on ingredients
· Chemical characterization: Mixtures
· Description: Mixture of substances listed below with nonhazardous additions.
· Dangerous components
 Aquatic Acute 1, H400; Aquatic Chronic 1, H410;  Tox. 4, H302; Acute Tox. 4, H332; Skin Sens. 1, H317 · Additional information: For the wording of the listed risk phrases refer to section 16.
4 First aid measures
· Description of first aid measures
· After inhalation: Supply fresh air; consult doctor in case of complaints.
· After skin contact: Generally the product does not irritate the skin.
· After eye contact: Rinse opened eye for several minutes under running water.
· After swallowing: If symptoms persist consult doctor.
· Information for doctor:
· Most important symptoms and effects, both acute and delayed No further relevant information available.
· Indication of any immediate medical attention and special treatment needed
No further relevant information available. 5 Firefighting measures
· Extinguishing media
· Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam. · Special hazards arising from the substance or mixture No further relevant information available.
· Advice for firefighters
· Protective equipment: No special measures required.
Safety data sheet
According to Regulatin 1907/2006/EC, Article 31 and Regulation 1272/2008/EC
Trade name: Impregnator for wood "AQUA"
6 Accidental release measures
· Personal precautions, protective equipment and emergency procedures Not required.
· Environmental precautions
Do not allow product to reach sewage system or any water course. Inform respective authorities in case of seepage into water course or sewage system. Do not allow to enter sewers/ surface or ground water. · Methods and material for containment and cleaning up
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). · Reference to other sections
See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. 7 Handling and storage
· Handling:
· Precautions for safe handling No special precautions are necessary if used correctly.
· Information about fire and explosion protection: No special measures required.
· Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles: No special requirements.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions: None.
· Specific end use(s) No further relevant information available.
8 Exposure controls / personal protection
· Additional information about design of technical facilities: No further data; see item 7.
· Control parameters
· Ingredients with limit values that require monitoring at the workplace
The product does not contain any relevant quantities of materials with critical values that have to be · Additional information: The lists valid during the making were used as basis.
· Exposure controls
· Personal protective equipment:
· General protective and hygienic measures: Wash hands before breaks and at the end of work.
· Respiratory protection: Not required.
· Protection of hands:
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ Selection of the glove material on consideration of the penetration times, rates of diffusion and the · Material of gloves:
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be Safety data sheet
According to Regulatin 1907/2006/EC, Article 31 and Regulation 1272/2008/EC
Trade name: Impregnator for wood "AQUA"
· Penetration time of glove material:
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be · Eye / face protection: Goggles recommended during refilling
9 Physical and chemical properties
· Information on basic physical and chemical properties
· General Information
· Appearance:
Form:
Colour:
· Odour:
· Odour threshold:
· pH-value at 20°C:
· Change in condition
Melting point / Melting range:
Boiling point / Boiling range:
· Flash point:
· Flammability (solid, gaseous):
· Ignition temperature:
Decomposition temperature:
· Self-igniting:
· Danger of explosion:
Product does not present an explosion hazard. · Explosion limits:
Lower:
Upper:
· Vapour pressure:
· Density:
· Relative density:
· Vapour density:
· Evaporation rate:
· Solubility in / Miscibility with
Water:
· Segregation coefficient (n-octanol/water): Not determined.
· Viscosity
dynamic:
kinematic:
· Solvent content:
Organic solvents:
VOC (EC):
· Other information:
No further relevant information available. Safety data sheet
According to Regulatin 1907/2006/EC, Article 31 and Regulation 1272/2008/EC
Trade name: Impregnator for wood "AQUA"
10 Stability and reactivity
· Reactivity
· Chemical stability
· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
· Possibility of hazardous reactions No dangerous reactions known.
· Conditions to avoid No further relevant information available.
· Incompatible materials No further relevant information available.
· Hazardous decomposition products No dangerous decomposition products known.
11 Toxicological information
· Information on toxicological effects
· Acute toxicity:
· Primary irritant effect
· on the skin: No irritant effect.
· on the eye: No irritating effect.
· Sensitization: No sensitizing effects known.
12 Ecological information
· Toxicity
· Acquatic toxicity No further relevant information available.
· Persistence and degradability No further relevant information available.
· Behaviour in environmental systems:
· Bioaccumulative potential No further relevant information available.
· Mobility in soil No further relevant information available.
· Ecotoxical effects:
· Remark: Very toxic for fish
· Additional ecological information:
· General notes:
Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water Do not allow product to reach ground water, water course or sewage system. Danger to drinking water if even small quantities leak into the ground. Also poisonous for fish and plankton in water bodies. · Results of PBT and vPvB assessment
· PBT: Not applicable.
· vPvB: Not applicable.
· Other adverse effects No further relevant information available.
13 Disposal considerations
· Waste treatment methods
· Recommendation:
Must not be disposed together with household garbage. Do not allow product to reach sewage system. · Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.
Safety data sheet
According to Regulatin 1907/2006/EC, Article 31 and Regulation 1272/2008/EC
Trade name: Impregnator for wood "AQUA"
· Recommended cleansing agents: Water, if necessary together with cleansing agents.
14 Transport information
· Land transport ADR / RID (cross-border)
· ADR / RID class:
9 Miscellaneous dangerous substances and articles. · Danger code (Kemler):
· UN Number:
· Packaging group:
· Hazard label:
· Special marking:
· UN proper shipping name: 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
(Permethrin, 1-octyl-2-pyrrolidone) · Tunnel restriction code:
· Maritime transport IMDG
· IMDG Class:
· UN Number:
· Label:
· Packaging group:
· EMS Number:
· Marine pollutant:
· Proper shipping name:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Permethrin, 1-octyl-2-pyrrolidone) · Air transport ICAO-TI and IATA-DGR
· ICAO / IATA Class:
· UN / ID Number:
· Label:
· Special marking:
· Packaging group:
· Proper shipping name:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Permethrin, 1-octyl-2-pyrrolidone) · UN "Model Regulation":
UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., 9, III · Environmental hazards Product contains environmentally hazardous substances: Permethrin
· Special precautions for user: Warning: Miscellaneous dangerous substances and articles.
Safety data sheet
According to Regulatin 1907/2006/EC, Article 31 and Regulation 1272/2008/EC
Trade name: Impregnator for wood "AQUA"
· Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code: Not applicable.
15 Regulatory information
· Safety, health and environmental regulations / legislation specific for the substance or mixture
· Labelling according to EU guidelines
The product has been classified and marked in accordance with EU Directives / Ordinance on Hazardous · Code letter and hazard designation of product:
 N Dangerous for the environment · Risk phrases:
50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. · Safety phrases:
29/56 Do not empty into drains, dispose of this material and its container at hazardous or special waste Use appropriate container to avoid environmental contamination. This material and its container must be disposed of as hazardous waste. · Special labelling of certain preparations:
Contains Permethrin. May produce an allergic reaction. · Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. · Relevant phrases:
H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H410 Very toxic to aquatic life with long lasting effects. H411 Toxic to aquatic life with long lasting effects.
R20/22 Harmful by inhalation and if swallowed. May cause sensitisation by skin contact. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. · Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road) RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous Goods by Rail) IMDG: International Maritime Code for Dangerous Goods IATA: International Air Transport Association IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA) ICAO: International Civil Aviation Organization ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO) GHS: Globally Harmonized System of Classification and Labelling of Chemicals VOC: Volatile Organic Compounds (USA, EU)

Source: http://www.selt.bg/uploads/documents/MSDS_AQUA%20Impregnator%20for%20wood_EN.pdf